60种农药的液相色谱、标准溶液定量离子色谱图.docx

附录A（资料性）60种农药的化学信息、分析参数、检出限、定量限饲料中60种农药及其代谢物的化学信息、分析参数、检出限和定量限见表A.1表A.160种农药及代谢物的化学信息、分析参数、检出限、定量限序号中文名称英文名称CAS号纯度检出限定量限溶剂gkgg&g1阿维菌素abameciin71751-41-2>90%620甲醇2胺菊酯tetramethrin7696-12-0>90%0.65丙酮3毗虫咻imidacloprid105827-78-9>90%0.65甲醇4毗理雄菌酯Pyraclostrobin175013-18-0>90%0.35丙酮5丙环哇propiconazole60207-90-1>90%1.815甲醇6丙溟磷profenofbs41198-08-7>90%1550丙酮7虫酰胧tebuIenozide112410-23-8>90%0.35甲醉8除虫服diflubenzuron35367-38-5>90%0.245甲醇9故百虫trichlorfon52-68-6>90%310丙酮IO敌草隆diuron330-54-1>90%0.65甲醇11敌敌畏dichlorvos62-73-7>90%1.510丙酮12皖虫眯ace(amiprid135410-20-7>90%0.35甲醇13咤酰菌胺boscalid188425-85-6>90%1.25甲醇14毒死婢Chlorpyrifos2921-88-2>90%1.25丙酮15对硫磷parathion56-38-2>90%310乙月青16多菌灵carbendazim10605-21-7>90%0.65乙脯17多杀霉素Spinosad131929-60-7>90%0.65甲醇18二苯胺diphenylamine122-39-4>90%1550甲醇19二嗪磷diazinon333-41-5>90%0.245环己烷20械胺鼠菊酯Iau-Fluvalinate102851-06-9>90%2.410丙酮21氟虫睛Fipronil120068-37-3>90%0.065乙腾氨虫睛碉fipronil-sulfbne120068-36-2>90%0.155丙酮械虫腊硫酸（亚飒）fipronil-sulfide120067-83-6>90%0.065丙酮氟甲睛fipronil-desulfinyl205650-65-3>90%0.65丙酮22氟硅嘎Ausilazole85509-19-9>90%0.125乙储23甲拌磷phorate298-02-2>90%0.155乙睛甲拌磷飒phoratesulfone2588-04-7>90%510乙月青甲拌磷亚碗phoratesulfoxide2588-03-6>90%510乙脯24甲基硫菌灵thiophanate-methyl23564-05-8>90%2.45甲醇25甲基异柳磷isofenphos-methyl99675-03-3>90%0.155丙酮26甲硫威methiocarb2032-65-7>90%0.65异丙醇甲硫威碉methiocarbsulfone2179-25-1>90%510异丙醉序号中文名称英文名称CAS号纯度检出限定量限溶剂gkgg&g甲硫威亚飒methiocarbsulfoxide2635-10-1>90%510异丙醉27甲蔡威carbaryl63-25-2>90%0.35甲醇28甲粗菊酯fenpropathrin64257-84-7>90%1.25乙腊29甲霜灵metalaxyl57837-19-1>90%0.125甲苯30久效磷monocrotophos6923-22-4>90%0.65甲醇31抗螃威pirimicarb23103-98-2>90%0.125乙腊脱甲基抗螃威pirimicarb-desmethyl30614-22-3>90%510乙睛脱甲基甲酰胺基抗蝇威pirimicarb-desmethyl-formamido27218-04-8>90%510乙脯32克百威carbofuran1563-66-2>90%0.35甲醇3-羟基克百威3-hydroxycarbofuran16655-82-6>90%1.25乙酸乙酯33噎氧灵quinoxyfen124495-18-7>90%0.65甲醇34乐果dimethoate60-51-5>90%0.065丙酮35联苯菊酯bifenthrin82657-04-3>90%1.25丙酮36氯毗嘴横隆halosulfuron-methyl100784-20-1>90%0.65乙脯37马拉硫磷malathion121-75-5>90%0.245乙腊马拉氧磷malaoxon1634-78-2>90%510乙睛38嘴菌酯azoxystrobin131860-33-8>90%0.155丙酮39灭多威methomyl16752-77-5>90%0.65丙酮40灭线磷ethoprophos131948-4>90%510甲醇41三环嘎tricyclazole41814-78-2>90%0.65乙脯42三哇醇triadimenol55219-65-3>90%4.85乙腊43三嚏酮Iriadimefon43121-43-3>90%9.632甲醉44杀扑磷methidathion950-37-8>90%0.2410甲醇45水胺硫磷isocarbophos24353-61-5>90%1550乙脂46萎锈灵carboxin5234-68-4>90%0.245甲醉47戊哇醇tebuconazol804434-0>90%0.245乙储48烯畦醇diniconazol76714-88-0>90%1.25甲醇49辛硫磷phoxim14816-18-3>90%1.25甲呼50亚胺硫磷phosmet732-11-6>90%0.155乙脯氧亚胺硫磷phosmetoxon3735-33-9>90%510乙腊51氧化萎锈灵oxycarboxin5259-88-1>90%0.125乙脂52乙拌磷disulfbton298-04-4>90%1.25甲醇内吸磷-S-碉demeton-S-sulfbne2496-91-5>90%510甲醇内吸磷-S-亚飒(Iemeton-S-Sulfoxide2496-92-6>90%510甲醇乙拌磷碉disulfbtonsulfone2497-06-5>90%510甲醇序号中文名称英文名称CAS号纯度检出限定量限溶剂gkgg&g乙拌磷亚硼disulfbtonsulfoxide2497-07-6>90%510甲醉53异嗯哇草酮isoxaflutole141112-29-0>90%0.65乙脯异嗯嗖草酮-二酮脂IsoxaflutoIe-Ciiketonitrile143701-75-1>90%510乙腊54乙硫磷eihion563-12-2>90%510甲醇55乙霉威diethofencarb87130-20-9>90%0.125甲醇56乙哝硫磷etrimfbs38260-54-7>90%510甲醇57异丙威isoprocarb2631-40-5>90%0.65甲醇58抑霉一imazalil35554-44-0>90%1.55甲醇59苛虫威indoxacarb144171-61-9>90%0.65甲醇60仲丁灵butralin33629-47-9>90%0.35丙酮附录B(资料性)60种农药的液相色谱串联质谱分析参数饲料中60种农药及其代谢物的液相色谱一串联质谱分析参数见表B.1表B.160种农药及代谢物的60种农药的液相色谱一串联质谱分析参数序号保留时间中文名称英文名称离子类型QlQ3去簇电压(V)碰撞能量(eV)116.72阿维菌素abamectin定量离子890.5305.18()45定性离子890.5567.18020214.06胺菊酯tetramethrin定量离子332.2164.15539定性离子332.2135.1553932.99毗虫咻imidacloprid定量离子256.1209.16031定性离子238181551445.67叱哩雄菌酯Pyraclostrobin定量离子3881635035定性离子3881945017510.46丙环喋propiconazole定量离子3421598045定性离子342698047613.13丙滨磷profenofbs定量离子3733037027定性离子3733457()1875.53虫酰胧Cebu