合成路径训练答案.docx

2024届高三化学二轮复习之微专题系列1oin1.nZ一一，、侬破险rYZnZHCNQ1.2. CH3CH2OH-h->CH3CH-WV'UH'N.NH,Q1./VgNJNHxNNXZCH3CH2OH、cdfwv1H浓琉球>CH3CU1JC2H5微专题3-1合成路径书写专项训练（1）答案i.(丫NaII×C(K)CHii.HH().YnNaOH,HtOrV<)'_Br'_M)l3. ClsNaoH醇溶液4. I*9Pa5. 小小0(6)CH3CHO-IaU11n：U入MgBrC2)H2OH*1C：6.00HNaClO4fs=0NaBH4OHCH1ONa/'1¼¼h一0CHOCHO0CHz=CHCHO人定条件一人催化剂1.JUOH00IIIH3C-CH-CH2-C-CH33H3C-CH=CH-C-CH3OH产OH1,NiC2H5(XX3CH2CH2C2H5CXCH2CH21ch2ch2cxxxh5/CH2CH2CX)OC2H5OOHKSz×iHNiOHOHC2HQNa)CH3COOC2H5dmf1.<xmH.C2H5ONaZC2H5OH-CH3Br-Br19.CH3CHzOHWeIK.,CHjCOOC2H5COOCjHsC(COOCtH5/NaHIi.H*H2O,微专题3-2合成路径书写专项训练（2）答案OHZ=为%O/O?催化剂催化剂,加热Cu,加热CHO氢氧化钠溶液4.6.HOCHOHC-CH2催化剂,加热CHOHC=CH0一定条件CHOrHI.-ECc4lIHjn5.OC-O-CN吧“令血(6)ClCHaX)H4NCCHCOoH-IICH1CHH-ENHCH7CHCOiOH(3分)CH18.2。H酸性KMnOJ溶整°°11SOCl2O9?()。IIIC(XX：2HsCHj)COej1.-VA/NWH一定条件-NHzCH2CHC(X)H>、.ICH3c°clQ31PdCl2(PPh3)2CuIOC(X)NaCH溶液CuJlZXcINaH'QlOIC(X)NaotoJ10.出赛与驾NH11.O八0C人、A1.A()H0“QohCH1COOH、OCH3CH2CH2Br，0>jlxCH3NaIIN¼Hj1QNHl0ToCHOAcOHZ(CH2)5NHO12.OHO17.IOH18.19.H2QlCACH2=CH2COOC2HSK2CO5PhCH2OOHCOoC、HS.-5CH3CH2COOC2H5COOGH$PhCHQa5PhCH2CICOOCSH5<Ho,fifJCH2=CHHCl>CH3CH2ClCMNH2、>CH2CH2OHHNUYH3NH3%分HNlCH2CH2OHh3c-nn-ch2ch3OH-三l*BrBrNCCN-HCCOOH屿微专题3-3合成路径书写专项训练（3）答案1.CIuHGH(IUHolOUHIINaNH,CH【“HJ,卜*cmikhcc3h<HINaOHHjO10.2C三CHOHDBB>暮云逆)H2C=CH2Br2CCI4-BrBrNaOHZH2OAHOOH(7)CH3CH2CH2OH20.BrBrIIC*H,C'H2CHX,H()CH3催化剂CH1CH1CHOCH3CH2CHO.7,“,二独小CH1CH2CH=CCHoWNaOH溶液/CH3BrBrIIZnCHVHzCH-C-C(X)H>CH3CH2CH=CXX)!I(3分CH3CH3COOH